| dc.contributor | Universidade Estadual Paulista (UNESP) | |
| dc.creator | Paim, Leonardo L. | |
| dc.creator | Hammer, Peter | |
| dc.creator | Stradiotto, Nelson Ramos | |
| dc.date | 2014-05-20T14:18:33Z | |
| dc.date | 2016-10-25T17:40:36Z | |
| dc.date | 2014-05-20T14:18:33Z | |
| dc.date | 2016-10-25T17:40:36Z | |
| dc.date | 2011-06-01 | |
| dc.date.accessioned | 2017-04-05T22:28:40Z | |
| dc.date.available | 2017-04-05T22:28:40Z | |
| dc.identifier | Electroanalysis. Malden: Wiley-blackwell, v. 23, n. 6, p. 1488-1496, 2011. | |
| dc.identifier | 1040-0397 | |
| dc.identifier | http://hdl.handle.net/11449/25594 | |
| dc.identifier | http://acervodigital.unesp.br/handle/11449/25594 | |
| dc.identifier | 10.1002/elan.201000723 | |
| dc.identifier | WOS:000291554700027 | |
| dc.identifier | http://dx.doi.org/10.1002/elan.201000723 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/870461 | |
| dc.description | The glassy carbon electrode was modified with a nickel pentacyanonitrosylferrate film by electrodeposition of Ni and subsequent derivatization with NaPCNF. The film was characterized by XPS and electrochemical methods. Cyclic voltammetry of the NiPCNF onto the GC shows a redox couple (Fe(III)/Fe(II)) with E(ol) of 538 mV (I(pa)/I(pc) around 1) and Delta E(p) of 93 mV in 0.5 mol L(-1) KNO(3), with a diffusion-controlled process. There was a decrease of anodic peak currents of the film in the presence of sulfide and 2-propanethiol due to a precipitation reaction on the film surface by nucleophilic attack. | |
| dc.description | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | |
| dc.description | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | |
| dc.language | eng | |
| dc.publisher | Wiley-Blackwell | |
| dc.relation | Electroanalysis | |
| dc.rights | info:eu-repo/semantics/closedAccess | |
| dc.subject | Mercaptan | |
| dc.subject | Sulfide | |
| dc.subject | Nickel pentacyanonitrosylferrate | |
| dc.subject | Cyclic voltammetry | |
| dc.subject | Square wave voltammetry | |
| dc.title | Electrochemical Behavior of a Glassy Carbon Electrode Chemically Modified with Nickel Pentacyanonitrosylferrate in Presence of Sulfur Compounds | |
| dc.type | Otro | |
