dc.contributorLAURA OLIVEIRA LAGO, UNIVERSIDADE FEDERAL DO RIO GRANDE DO SUL; PAWEL SWIT, UNIVERSITY OF SILESIA; MAIRON MOURA DA SILVA, UNIVERSIDADE FEDERAL RURAL DE PERNAMBUCO; ALINE TELLES BIASOTO MARQUES, CNPMA; JULIANE WELKE, UNIVERSIDADE FEDERAL DO RIO GRANDE DO SUL; LIDIA MONTERO, UNIVERSIDAD AUTÓNOMA DE MADRID; MIGUEL HERRERO, UNIVERSIDAD AUTÓNOMA DE MADRID.
dc.creatorLAGO, L. O.
dc.creatorSWIT, P.
dc.creatorSILVA, M. M. da
dc.creatorBIASOTO, A. C. T.
dc.creatorWELKE, J.
dc.creatorMONTERO, L.
dc.creatorHERRERO, M.
dc.date2023-08-30T13:23:54Z
dc.date2023-08-30T13:23:54Z
dc.date2023-08-30
dc.date2023
dc.date.accessioned2023-09-05T03:08:22Z
dc.date.available2023-09-05T03:08:22Z
dc.identifierJournal of Chromatography A, v. 1704, article 464131, 2023.
dc.identifierhttp://www.alice.cnptia.embrapa.br/alice/handle/doc/1156216
dc.identifierhttps://doi.org/10.1016/j.chroma.2023.464131
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/8638612
dc.descriptionAbstract: The typical phenolic profile in grapes is characterized by its complexity both in terms of number of diverse chemical structures and their variation during ripening. Besides, the specific phenolic composition of grapes directly influences the presence of those components in the resulting wine. In this contribution, a new method based on the application of comprehensive two-dimensional liquid chromatography coupled to a diode array detector and tandem mass spectrometry has been developed to obtain the typical phenolic profile of Malbec grapes cultivated in Brazil. Moreover, the method has been demonstrated to be useful to study how the phenolic composition in grapes evolved during a 10-week ripening period. Main detected compounds in grapes and in the wine derived from them were anthocyanins, although a good number of polymeric flavan-3-ols were also tentatively identified, among other compounds. Results show how the amount of anthocyanins present in grapes was increased during ripening up to 5-6 weeks and then decreased towards week 9. The two-dimensional approach applied was demonstrated to be useful for the characterization of the complex phenolic profile of these samples, involving more than 40 different structures and has the potential to be further applied to the study of this important fraction is different grapes and wines systematically.
dc.languageIngles
dc.languageen
dc.rightsopenAccess
dc.subjectOrganic Chemistry
dc.subjectGeneral Medicine
dc.subjectUva
dc.subjectMaturação
dc.subjectVinho
dc.subjectAnálise Química
dc.subjectCromatografia
dc.subjectAntocianina
dc.subjectComposto Fenólico
dc.subjectGrapes
dc.subjectWines
dc.subjectPhenolic compounds
dc.subjectLiquid chromatography
dc.subjectanalytical chemistry
dc.subjectbiochemistry
dc.titleEvolution of anthocyanin content during grape ripening and characterization of the phenolic profile of the resulting wine by comprehensive two-dimensional liquid chromatography.
dc.typeArtigo de periódico


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