Nucleation kinetics of crystalline phases from a kaolinitic body used in the processing of red ceramics

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorSilva, R. A.
dc.creatorTeixeira, S. R.
dc.creatorSouza, A. E.
dc.creatorSantos, Dayse Iara dos
dc.creatorRomero, M.
dc.creatorMa. Rincon, J.
dc.date2014-05-20T13:23:00Z
dc.date2016-10-25T16:44:05Z
dc.date2014-05-20T13:23:00Z
dc.date2016-10-25T16:44:05Z
dc.date2011-04-01
dc.date.accessioned2017-04-05T19:56:07Z
dc.date.available2017-04-05T19:56:07Z
dc.identifierApplied Clay Science. Amsterdam: Elsevier B.V., v. 52, n. 1-2, p. 165-170, 2011.
dc.identifier0169-1317
dc.identifierhttp://hdl.handle.net/11449/6854
dc.identifierhttp://acervodigital.unesp.br/handle/11449/6854
dc.identifier10.1016/j.clay.2011.02.019
dc.identifierWOS:000289610000023
dc.identifierhttp://dx.doi.org/10.1016/j.clay.2011.02.019
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/855670
dc.descriptionThe crystallization kinetics of red ceramic raw material from the western part of São Paulo State, Brazil, was examined by differential thermal analysis (DTA) and X-ray diffraction (XRD). The chemical composition of the clay sample was determined by X-ray fluorescence (XRF). Non-isothermal crystallization kinetic methods have been applied to the study of the mechanism of crystallization in this kaolinitic material. The exothermic peak shifted to higher temperatures (945 to 974 degrees C) with increasing heating rate (10 to 50 degrees C/min). The average activation energies determined by the Kissinger method (787 +/- 85 kJ/mol) and the Ligero method (721 +/- 32 kJ/mol) are in agreement. The Avrami constant n obtained by the Ligero method and the m parameter (Matusita method) values were between 1 and 1.5, which indicate a three-dimensional crystal growth with polyhedral morphology and surface nucleation as the dominant mechanism. X-ray diffraction data indicate that this activation energy is not associated with the crystallization of mullite. Scanning electron microscopy (SEM) images of fired (1000 and 1190 degrees C) samples show their densification during the sinterization process. (C) 2011 Elsevier B.V. All rights reserved.
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.languageeng
dc.publisherElsevier B.V.
dc.relationApplied Clay Science
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectKinetics
dc.subjectCrystallization
dc.subjectKaolin
dc.subjectRed ceramic
dc.subjectMullite
dc.titleNucleation kinetics of crystalline phases from a kaolinitic body used in the processing of red ceramics
dc.typeOtro


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