| dc.creator | Ledesma, Brenda C. | |
| dc.creator | Beltramone, Andrea R. | |
| dc.date | 2022-06-03T23:03:19Z | |
| dc.date | 2022-06-03T23:03:19Z | |
| dc.date | 2021 | |
| dc.date.accessioned | 2023-08-31T14:36:17Z | |
| dc.date.available | 2023-08-31T14:36:17Z | |
| dc.identifier | http://hdl.handle.net/20.500.12272/6606 | |
| dc.identifier | - | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/8548300 | |
| dc.description | Monometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done in order to understand structure-activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetallic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support. | |
| dc.description | Fil: Ledesma, Brenda C.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina. | |
| dc.description | Fil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina. | |
| dc.format | pdf | |
| dc.language | eng | |
| dc.rights | openAccess | |
| dc.rights | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | |
| dc.rights | Andrea R. Beltramone | |
| dc.rights | _X_Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos).
_X_No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales.
_X_Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).
_X_Compartir igual (Share Alike): La explotación autorizada incluye la creación de obras derivadas siempre que se mantenga la misma licencia al ser divulgadas. | |
| dc.subject | Titanium | |
| dc.subject | platinum | |
| dc.subject | iridium | |
| dc.subject | modified mesoporous carbon | |
| dc.subject | 5-hydroximethylfurfural | |
| dc.subject | 2,5-dimethylfuran provide | |
| dc.title | Biofuel production using ordered mesoporous carbons with modified carbonaceous structure | |
| dc.type | info:eu-repo/semantics/conferenceObject | |
| dc.type | publisherVersion | |
