Equilibrio multifásico de mezclas binarias y ternarias de carbonato de dietilo (DEC), agua y etanol
Multiphase equilibrium for binary and ternary mixtures containing diethyl carbonate (DEC), water and ethanol
| dc.creator | Arango Montoya, Isabel Cristina | |
| dc.creator | Villa Holguín, Aída Luz | |
| dc.date | 2022-03-16T16:23:28Z | |
| dc.date | 2022-03-16T16:23:28Z | |
| dc.date | 2012 | |
| dc.date.accessioned | 2023-08-28T20:23:31Z | |
| dc.date.available | 2023-08-28T20:23:31Z | |
| dc.identifier | 0120-100X | |
| dc.identifier | 2145-8480 | |
| dc.identifier | http://hdl.handle.net/10495/26661 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/8478453 | |
| dc.description | RESUMEN: En este trabajo se reporta la solubilidad del DEC en agua, y la curva de solubilidad del sistema ternario carbonato de dietilo (DEC) + agua + etanol entre 296,15 y 338,15K. Se confirma la presencia de azeótropos binarios con las graficas del equilibrio líquido vapor x-y de los constituyentes binarios a 353,15K y 363,15K y la ausencia de azeótropos ternarios mediante la regla azeotrópica. Los datos experimentales se correlacionan con los modelos termodinámicos NRTL y UNIQUAC, encontrándose que ambos modelos representan satisfactoriamente el sistema. Los parámetros de interacción binaria para el sistema ternario y sus sistemas binarios se reportan en función de la temperatura. | |
| dc.description | ABSTRACT: The solubility of DEC in water and the solubility curves of the diethyl carbonate (DEC) + water + ethanol ternary system between 296.15 and 338.15K are reported. The results confirm the presence of binary azeotropes using plots x-y of the binary constituents at 353.15K and 363.15K and the absence of ternary azeotropes by the azeotropic rule. The experimental data were correlated with the NRTL and UNIQUAC models, showing that both models provide a good representation of the system. The binary interaction parameter for the ternary system and their binary systems are reported in function of temperature in this work. | |
| dc.description | COL0001941 | |
| dc.format | 7 | |
| dc.format | application/pdf | |
| dc.format | application/pdf | |
| dc.language | spa | |
| dc.publisher | Universidad industrial de Santander, Escuela de ingeniería química | |
| dc.publisher | Catálisis Ambiental | |
| dc.publisher | Bucaramanga, Colombia | |
| dc.relation | Rev. ion | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.rights | http://creativecommons.org/licenses/by/2.5/co/ | |
| dc.rights | http://purl.org/coar/access_right/c_abf2 | |
| dc.rights | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | Azeotropos | |
| dc.subject | Azeotropes | |
| dc.subject | Mezclas binarias | |
| dc.title | Equilibrio multifásico de mezclas binarias y ternarias de carbonato de dietilo (DEC), agua y etanol | |
| dc.title | Multiphase equilibrium for binary and ternary mixtures containing diethyl carbonate (DEC), water and ethanol | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
| dc.type | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.type | https://purl.org/redcol/resource_type/ART | |
| dc.type | Artículo de investigación |