Artigo de periódico
Enantioselective synthesis of (R)-isocarvone from (S)-perillaldehyde
Autor
Gamba, Douglas
Pisoni, Diego dos Santos
Costa, Jessie Sobieski da
Petzhold, Cesar Liberato
Borges, Antônio César de Amorim
Ceschi, Marco Antonio
Resumen
Este trabalho descreve a preparação enantiosseletiva da (R)-(+)-isocarvona, (S)-(-)-5-isopropenilcicloex-2-enona e (S)-(-)-3-isopropenilcicloexanona, a partir do (S)-(-)-perilaldeído. Estes compostos podem ser usados como blocos de construção importantes para a síntese orgânica. This work describes the enantioselective preparation of (R)-(+)-isocarvone, (S)-(-)-5-isopropenylcyclohex-2-enone and (S)-(-)-3-isopropenylcyclohexanone starting from (S)-(-)-perillaldehyde. These compounds hold the prospect of serving as useful chiral building blocks or intermediates in organic synthesis.