| dc.creator | Cozzarín, Melina Vanesa | |
| dc.creator | Romano, Rosana Mariel | |
| dc.date | 2017-05 | |
| dc.date | 2022-12-27T14:07:56Z | |
| dc.date.accessioned | 2023-07-15T09:16:30Z | |
| dc.date.available | 2023-07-15T09:16:30Z | |
| dc.identifier | http://sedici.unlp.edu.ar/handle/10915/147714 | |
| dc.identifier | issn:2365-6549 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/7487419 | |
| dc.description | The photochemistry of FC(O)SSCl isolated in solid Ar was investigated on the basis of the IR spectra of the matrices before and after different times of broad-band UV-visible irradiation. The first process occurring on broad-band UV-visible irradiation was the transformation of the syn-gauche form of FC (O)SSCl into the anti-gauche conformer. FC(O)SCl and ClFC=O were produced, involving the loss of one or two sulfur atoms, respectively. Other mechanisms have originated CO···ClSSF, OCS···ClSF, OCS···ClF, CO···ClSF and CS₂···ClF molecular complexes, identified by the comparison of the experimental IR spectra with that simulated with DFT (B3LYP/6-311+G*) calculations, with the exception of OCS···ClF, which was assigned on the basis of the comparison with reported IR absorptions. | |
| dc.description | Centro de Química Inorgánica | |
| dc.format | application/pdf | |
| dc.format | 4092-4098 | |
| dc.language | en | |
| dc.rights | http://creativecommons.org/licenses/by/4.0/ | |
| dc.rights | Creative Commons Attribution 4.0 International (CC BY 4.0) | |
| dc.subject | Ciencias Exactas | |
| dc.subject | Química | |
| dc.subject | Conformers | |
| dc.subject | FTIR | |
| dc.subject | Matrix-Isolation | |
| dc.subject | Molecular Complexes | |
| dc.subject | Photochemistry | |
| dc.title | Unimolecular Photochemical Mechanisms of FC(O)SSCl Isolated in Solid Ar | |
| dc.type | Articulo | |
| dc.type | Articulo | |
