dc.creatorPodestá, José J.
dc.creatorPiatti, Roberto C. V.
dc.creatorArvia, Alejandro Jorge
dc.date1990
dc.date2022-02-11T15:38:21Z
dc.date.accessioned2023-07-15T05:15:20Z
dc.date.available2023-07-15T05:15:20Z
dc.identifierhttp://sedici.unlp.edu.ar/handle/10915/130945
dc.identifierissn:0021-891X
dc.identifierissn:1572-8838
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/7472669
dc.descriptionThe anodic and cathodic behaviour of polycrystalline Pt in sodium hypophosphite solutions has been investigated by cyclic voltammetry. In acid solutions the voltammograms show that, owing to the presence of the reducing agent, electrooxidation of species related to H₃PO₃ occurs in the potential range 0.6 to 1.4 V with respect to NHE. In alkaline solutins the presence of NaH₂PO₂ partially inhibits the HER and displaces the formation of the oxygen monolayer on platinum to higher potentials. The voltammetric peaks are attributed to the electrooxidation of the products resulting from the chemical decomposition of NaH₂PO₂ in contact with the Pt surface.
dc.descriptionInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
dc.formatapplication/pdf
dc.format245-251
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-sa/4.0/
dc.rightsCreative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.subjectQuímica
dc.subjectFísica
dc.subjectOxygen
dc.subjectSodium
dc.subjectPhysical Chemistry
dc.subjectAqueous Solution
dc.subjectPlatinum
dc.titleVoltammetric behaviour of platinum in aqueous solutions containing sodium hypophosphite
dc.typeArticulo
dc.typeArticulo


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