| dc.creator | Castells, Reynaldo César | |
| dc.creator | Arancibia, Eleuterio L. | |
| dc.creator | Nardillo, Ángel Miguel | |
| dc.date | 1993 | |
| dc.date | 2022-09-21T14:19:32Z | |
| dc.date.accessioned | 2023-07-15T05:13:37Z | |
| dc.date.available | 2023-07-15T05:13:37Z | |
| dc.identifier | http://sedici.unlp.edu.ar/handle/10915/142475 | |
| dc.identifier | issn:0095-9782 | |
| dc.identifier | issn:1572-8927 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/7472561 | |
| dc.description | The retention behavior of eight halomethanes and four saturated hydrocarbons was measured in gas chromatographic stationary phases consisting in tri-n-octylamine (TOA), squalane (SQ) and six TOA+SQ mixtures, at 55.0, 58.5, 62.5 and 65.0°C. Equlibrium constants for complex formation were extracted from experimental data by using a lattice model developed by Martire. The results may be interpreted in terms of the formation of weak hydrogen-bonded complexes, with sociation constants of about 0.13 L-mol⁻¹ for haloforms and 0.07 L-mol⁻¹ for dihalomethanes at 60°C. | |
| dc.description | Centro de Investigación y Desarrollo en Tecnología de Pinturas | |
| dc.format | application/pdf | |
| dc.format | 85-94 | |
| dc.language | en | |
| dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
| dc.rights | Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) | |
| dc.subject | Química | |
| dc.subject | Tri-n-octylamine | |
| dc.subject | Halomethanes | |
| dc.subject | Molecular association | |
| dc.subject | Hydrogen-bonded complexes | |
| dc.subject | Nonrandom mixtures | |
| dc.subject | Gas-liquid chromatography. | |
| dc.title | Halomethanes in tri-n-octylamine and squalane mixtures at infinite dilution | |
| dc.type | Articulo | |
| dc.type | Articulo | |
