Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide

dc.creatorArvia, Alejandro Jorge
dc.creatorGiordano, M. C.
dc.creatorPodestá, José J.
dc.date1969
dc.date2021-07-15T16:32:10Z
dc.date.accessioned2023-07-15T02:28:09Z
dc.date.available2023-07-15T02:28:09Z
dc.identifierhttp://sedici.unlp.edu.ar/handle/10915/121762
dc.identifierissn:0013-4686
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/7462063
dc.descriptionThe kinetics and mechanisms of the iodine and tri-iodide ion reduction and iodide and tri-iodide ion oxidation on platinum have been determined, from a study of the electrochemical kinetic behaviour of DMSO solutions containing an iodine/sodium-iodide ratio greater than one. The likely mechanisms are the same as those recently discussed for the iodine—sodium-iodide solutions in acetonitrile, and all comprise consecutive reaction schemes involving, for the processes in the anodic direction, an ion-plus-atom reaction as rate-determining step, and the reverse reaction for the cathodic processes.
dc.descriptionInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
dc.formatapplication/pdf
dc.format389-403
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by/4.0/
dc.rightsCreative Commons Attribution 4.0 International (CC BY 4.0)
dc.subjectCiencias Exactas
dc.subjectQuímica
dc.subjectKinetics
dc.subjectPlatinum
dc.subjectDMSO
dc.titleKinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium-iodide in dimethylsulphoxide
dc.typeArticulo
dc.typeArticulo


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