dc.creator | Martins, María Elisa | |
dc.creator | Castellano, Carlos E. | |
dc.creator | Calandra, Alfredo J. | |
dc.creator | Arvia, Alejandro Jorge | |
dc.date | 1978 | |
dc.date | 2021-05-31T13:43:35Z | |
dc.date.accessioned | 2023-07-15T01:52:45Z | |
dc.date.available | 2023-07-15T01:52:45Z | |
dc.identifier | http://sedici.unlp.edu.ar/handle/10915/119485 | |
dc.identifier | issn:0022-0728 | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/7459942 | |
dc.description | The electrochemical behaviour of the Au/SCN<sup>−</sup> (DMSO) interface is studied at 25°C≤T≤65°C, by means of the triangular potential sweep technique and the RDE. Within a relatively limited potential range the main electrode process is: 3 SCN<sup>−</sup>=(SCN)<sub>3</sub><sup>−</sup>+2e The kinetics of this reaction involves a mixed control. At higher potentials the electrodissolution of the base metal takes place. Side reactions occurring there make the overall process rather complex. The electrochemical behaviours of the Au/SCN<sup>−</sup> (DMSO) and Au/SCN<sup>−</sup> (ACN) are compared. | |
dc.description | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas | |
dc.format | application/pdf | |
dc.format | 45-53 | |
dc.language | en | |
dc.rights | http://creativecommons.org/licenses/by/4.0/ | |
dc.rights | Creative Commons Attribution 4.0 International (CC BY 4.0) | |
dc.subject | Ciencias Exactas | |
dc.subject | Química | |
dc.subject | Electrochemical behaviour | |
dc.subject | Gold | |
dc.subject | SCN−/dimethylsulfoxide solutions | |
dc.title | Electrochemical kinetics of gold electrodes in SCN<sup>−</sup>/dimethylsulfoxide solutions | |
dc.type | Articulo | |
dc.type | Articulo | |