dc.creatorBuffoni, Ivana Natalia
dc.creatorGatti, Martín Nicolás
dc.creatorSantori, Gerardo Fabián
dc.creatorPompeo, Francisco
dc.creatorNichio, Nora Nancy
dc.date2017-05-04
dc.date2020-08-24T15:34:02Z
dc.date.accessioned2023-07-14T21:39:30Z
dc.date.available2023-07-14T21:39:30Z
dc.identifierhttp://sedici.unlp.edu.ar/handle/10915/102956
dc.identifierhttps://www.sciencedirect.com/science/article/abs/pii/S0360319917313678?via%3Dihub
dc.identifierissn:0360-3199
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/7443909
dc.descriptionThis work studies 2 wt% Pt catalysts. The support is a SiO<sub>2</sub>-C composite whose main features are a high specific surface due to its mesoporosity, a higher thermal stability than the C support, and the absence of surface acid sites which could promote the dehydration reactions that produce coke precursors. The Pt/SiO<sub>2</sub>-C catalyst has very small metallic particles (d<sub>va</sub> = 1.37 nm) that favor the C-C bond cleavage reactions which allow obtaining total gas conversion at 450C. With this catalyst, it is possible to obtain high yields to H<sub>2</sub>, between 4 and 5, which indicates that the active sites promote the WGS reaction, even with glycerol concentrations of 30 and 50%. Pt/SiO<sub>2</sub>-C is a very stable catalyst since it loses only 10% of its initial activity after 66 h on stream and is resistant to sintering and coke deposition.
dc.descriptionFacultad de Ingeniería
dc.descriptionCentro de Investigación y Desarrollo en Ciencias Aplicadas
dc.formatapplication/pdf
dc.format12967-12977
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-sa/4.0/
dc.rightsCreative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.subjectCiencias Exactas
dc.subjectHydrogen
dc.subjectPlatinum
dc.subjectSteam reforming
dc.subjectGlycerol
dc.titleHydrogen from glycerol steam reforming with a platinum catalyst supported on a SiO<sub>2</sub>-C composite
dc.typeArticulo
dc.typeArticulo


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