dc.creatorSeré, Pablo Ricardo
dc.creatorEgli, Walter Alfredo
dc.creatorDi Sarli, Alejandro Ramón
dc.creatorDeyá, Marta Cecilia
dc.date2018
dc.date2020-05-11T17:26:52Z
dc.date.accessioned2023-07-14T20:16:53Z
dc.date.available2023-07-14T20:16:53Z
dc.identifierhttp://sedici.unlp.edu.ar/handle/10915/95576
dc.identifierissn:1059-9495
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/7438615
dc.descriptionSilanes are an interesting alternative to chromate-based surface treatments for temporary protection of electrogalvanized steel. In this work, the protective behavior of 3-mercaptopropyltrimethoxysilane (MTMO), 3-aminopropyltriethoxysilane (AMEO), or 3-glycidoxypropyltrimethoxysilane (GLYMO) films applied on electrogalvanized automotive quality steel sheets has been studied. The silane coating morphology, composition, and porosity were characterized by scanning electron microscopy (SEM), energydispersive x-ray spectroscopy (EDS), x-ray fluorescence, immersion in copper sulfate, and cyclic voltammetry. The corrosion protection was evaluated by polarization curves, electrochemical noise measurements, electrochemical impedance spectrometry, and accelerated humidity chamber tests. The results showed that the silanes protect temporarily electrogalvanized steel from corrosion. MTMO forms a relatively thick and cracked film. AMEO and GLYMO films were so thin that they could not be observed by SEM but silicon was detected by EDS. MTMO provided good temporary protection, being an alternative to replace Cr(VI) as protector of electrogalvanized steel.
dc.descriptionCentro de Investigación y Desarrollo en Tecnología de Pinturas
dc.formatapplication/pdf
dc.format1194-1202
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.subjectIngeniería Química
dc.subjectProtective films
dc.subjectElectrogalvanized
dc.subjectSilane
dc.subjectSurface treatment
dc.titlePreparation and characterization of silanes films to protect electrogalvanized steel
dc.typeArticulo
dc.typeArticulo


Este ítem pertenece a la siguiente institución