The nanoscopic principles of capacitive ion sensing interfaces

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversity of Oxford
dc.date.accessioned2020-12-12T02:36:30Z
dc.date.accessioned2022-12-19T21:18:20Z
dc.date.available2020-12-12T02:36:30Z
dc.date.available2022-12-19T21:18:20Z
dc.date.created2020-12-12T02:36:30Z
dc.date.issued2020-02-21
dc.identifierPhysical Chemistry Chemical Physics, v. 22, n. 7, p. 3770-3774, 2020.
dc.identifier1463-9076
dc.identifierhttp://hdl.handle.net/11449/201588
dc.identifier10.1039/c9cp05543f
dc.identifier2-s2.0-85080846659
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/5382222
dc.description.abstractHerein we discuss the operational principles of molecular interfaces that specifically recruit ions from an electrolyte solution and report this in a reagentless capacitive manner. At low ionic occupancy the response of the interface obeys a Debye-type phenomenon akin to classic image charge effects. At higher levels of occupancy, the response follows Thomas-Fermi screening and, significantly, is dependent on the electronic structure of the mesoscopic ion-receptor host-guest ensemble.
dc.languageeng
dc.relationPhysical Chemistry Chemical Physics
dc.sourceScopus
dc.titleThe nanoscopic principles of capacitive ion sensing interfaces
dc.typeArtículos de revistas


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