Thermal behaviour of binuclear cyclopalladated compounds containing anionic azo-ligands
| dc.contributor | Universidade Estadual Paulista (Unesp) | |
| dc.contributor | Univ Catolica Brasilia | |
| dc.date.accessioned | 2020-12-10T18:01:31Z | |
| dc.date.accessioned | 2022-12-19T20:08:02Z | |
| dc.date.available | 2020-12-10T18:01:31Z | |
| dc.date.available | 2022-12-19T20:08:02Z | |
| dc.date.created | 2020-12-10T18:01:31Z | |
| dc.date.issued | 2002-01-01 | |
| dc.identifier | Ecletica Quimica. Sao Paulo: Editora Unesp, v. 27, p. 201-210, 2002. | |
| dc.identifier | 0100-4670 | |
| dc.identifier | http://hdl.handle.net/11449/195728 | |
| dc.identifier | WOS:000179435100017 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/5376366 | |
| dc.description.abstract | This paper deals with the thermal behavior study of cyclopalladated complexes obtained from reactions of [Pd(dmba)N-3](2) (1), dmba = N,N-dimethylbenzylamine, with azole-compunds, such as, the anionic ligands pyrazolate (pz), imidazolate (imz) and 3,5-dimethyl-pyrazolate (3,5-dmpz), The characterization of the binuclear complexes [Pd(dmba)(mu-pz)](2) (2), [Pd(dmba)(mu-imz)](2) (3) and [Pd(dmba)(mu-3.5-dmpz)](2) (4) was carried out by elemental analysis, IR and NMR spectroscopy, Their thermal behaviour has been investigated and the final product was identified by X-ray powder diffractometry which showed the formation of Pd(0) as final decomposition product. | |
| dc.language | spa | |
| dc.publisher | Editora Unesp | |
| dc.relation | Ecletica Quimica | |
| dc.source | Web of Science | |
| dc.subject | cyclopalladated | |
| dc.subject | thermal analysis | |
| dc.subject | pyrazolate | |
| dc.subject | imidazolate | |
| dc.subject | 3,5-dimethyl-pyrazolate | |
| dc.title | Thermal behaviour of binuclear cyclopalladated compounds containing anionic azo-ligands | |
| dc.type | Artículos de revistas |