Spectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.

dc.contributorUniversidade Federal do Pará (UFPA)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2020-12-10T16:29:25Z
dc.date.accessioned2022-12-19T19:53:36Z
dc.date.available2020-12-10T16:29:25Z
dc.date.available2022-12-19T19:53:36Z
dc.date.created2020-12-10T16:29:25Z
dc.date.issued1999-11-01
dc.identifierQuimica Nova. Sao Paulo: Soc Brasileira Quimica, v. 22, n. 6, p. 787-789, 1999.
dc.identifier0100-4042
dc.identifierhttp://hdl.handle.net/11449/194542
dc.identifierWOS:000084027000003
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/5375178
dc.description.abstractcis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I, The series of compounds cis-[Fe(CO)(4)(HgX)(2)], X=Cl, Br, I shows an octahedral geometry around the iron atom with the two HgX groups cis to each other, In this paper the assignment for the carbonyl stretching modes and the calculation of their force constants were performed on the basis of the Cotton-Krainhanzel model, Taking into account all the data from the IR,Hg-199 NMR and UV-vis spectra it is possible to verify the influence of X on the electronic densities at the metallic centers.
dc.languagepor
dc.publisherSoc Brasileira Quimica
dc.relationQuimica Nova
dc.sourceWeb of Science
dc.subjectiron carbonyls
dc.subjectmercury
dc.subjectspectroscopic studies
dc.titleSpectroscopic studies of heterobimetallic carbonyls cis-[Fe(CO)(4)(HgX)(2)], X = Cl, Br, I.
dc.typeArtículos de revistas


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