Thermal behaviour of bambus[6]uril and its chloride caviplex

dc.contributorUniversidade de São Paulo (USP)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2019-10-05T21:44:58Z
dc.date.accessioned2022-12-19T18:22:11Z
dc.date.available2019-10-05T21:44:58Z
dc.date.available2022-12-19T18:22:11Z
dc.date.created2019-10-05T21:44:58Z
dc.date.issued2019-05-01
dc.identifierJournal Of Thermal Analysis And Calorimetry. Dordrecht: Springer, v. 136, n. 3, p. 1195-1199, 2019.
dc.identifier1388-6150
dc.identifierhttp://hdl.handle.net/11449/186714
dc.identifier10.1007/s10973-018-7755-0
dc.identifierWOS:000464699900019
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/5367752
dc.description.abstractThe present paper presents the thermal behaviour of methyl-bambus[6]uril in its anion-free and chlorine-included form. Our study was based on thermogravimetry associated to Fourier-transform infrared spectroscopy and differential scanning calorimetry. The compounds decompose after 300 degrees C and both forms of this macrocycle, contain four hydration water molecules. The main decomposition products are H2O, CO2, NH3 and isocyanic acid as we could detect by FTIR spectroscopy. Finally, we verified that the caviplex loses its chloride ion after 270 degrees C and may produce the anion-free macrocyle upon heating.
dc.languageeng
dc.publisherSpringer
dc.relationJournal Of Thermal Analysis And Calorimetry
dc.rightsAcesso aberto
dc.sourceWeb of Science
dc.subjectMethyl-bambus[6]uril
dc.subjectThermal behaviour
dc.subjectMacrocycle
dc.subjectCaviplex
dc.titleThermal behaviour of bambus[6]uril and its chloride caviplex
dc.typeArtículos de revistas


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