Electrocatalytic oxidation of ascorbic acid on mesostructured SiO 2 -conducting polymer composites

dc.contributormorallon@ua.es
dc.creatorSanchis, C.
dc.creatorMontilla, Francisco
dc.creatorHuerta, Francisco
dc.creatorRivero, Omar
dc.creatorRivero, Omar
dc.creatorHuerta, Francisco
dc.creatorMontilla, Francisco
dc.creatorSanchis, C.
dc.date2017-07-12T19:46:00Z
dc.date2017-07-12T19:46:00Z
dc.date2015-08
dc.date.accessioned2022-12-06T19:42:43Z
dc.date.available2022-12-06T19:42:43Z
dc.identifier0014-3057
dc.identifierhttp://hdl.handle.net/20.500.14076/3774
dc.identifierEuropean Polymer Journal
dc.identifier10.1016/j.eurpolymj.2015.06.004
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/5276961
dc.descriptionThe conducting self-doping copolymer poly(aniline-co-ABA) preserves its redox activity at pH values as high as 7. This observation was the starting point to synthesize an organic– inorganic hybrid composite able to electrochemically oxidize ascorbic acid molecules at that pH. The inorganic part of the catalytic element was an ordered mesoporous electrode-posit of SiO 2 , which has been used as the template for the electrochemical insertion of the self-doping copolymer. The oxidation of ascorbate ions at a fixed potential on this composite was studied by means of the kinetic model proposed by Bartlett and Wallace (2001). It was observed that the effective kinetic constant K ME increased significantly but, simultaneously , k 0 ME remained almost constant when the composite was employed as the electrocat-alytic substrate. These results were interpreted in the light of two combinations of kinetic constants, which strongly suggested that the increase in K ME should be ascribed to the improvement in electronic conductivity of the copolymer induced by the highly ordered silica template.
dc.formatapplication/pdf
dc.languageeng
dc.publisherElsevier Ltd
dc.relationhttp://www.sciencedirect.com/science/article/pii/S0014305715003080
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.rightshttp://creativecommons.org/licenses/by/4.0/
dc.sourceUniversidad Nacional de Ingeniería
dc.sourceRepositorio Institucional - UNI
dc.subjectHibrid materials
dc.subjectMesostructured SiO2
dc.subjectCopolymerization
dc.subjectCopolymer poly(aniline-co-ABA)
dc.subjectAscorbic acid
dc.titleElectrocatalytic oxidation of ascorbic acid on mesostructured SiO 2 -conducting polymer composites
dc.typeArtículos de revistas


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