Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step

dc.creatorPostigo, Al
dc.creatorKopsov, Sergey
dc.creatorZlotsky, Simon S.
dc.creatorFerreri, Carla
dc.creatorChatgilialoglu, Chryssostomos
dc.date.accessioned2014-07-25T21:22:57Z
dc.date.accessioned2022-11-09T15:00:30Z
dc.date.available2014-07-25T21:22:57Z
dc.date.available2022-11-09T15:00:30Z
dc.date.created2014-07-25T21:22:57Z
dc.date.issued2009
dc.identifierhttp://repositorio.ub.edu.ar/handle/123456789/2726
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/5167955
dc.description.abstractThe classical radical-based hydrosilylation reaction of organic compounds bearing C−C multiple bonds is usually carried out in organic solvents and is herein presented in water with both organic solvent-soluble and water-soluble substrates. Different initiation methods to accomplish the radical-induced hydrosilylation reaction of C−C multiple bonds in water with (Me3Si)3SiH are presented. In the thermal decomposition of azo compounds, the system comprising substrate, silane, and azo-initiator (ACCN) mixed in aqueous medium at 100 °C worked well for both hydrophilic and hydrophobic substrates, with the only variation that the amphiphilic thiol HOCH2CH2SH was also needed in the case of the water-soluble compounds.
dc.languageen
dc.publisherUniversidad de Belgrano - Facultad de Ciencias Exactas y Naturales - Proyectos de Investigación
dc.relationOrganometallics;2009, 28 (11), pp 3282–3287
dc.subjectHydrosilylation
dc.subjectMultiple Bonds
dc.subjectRadical Initiation Step
dc.subjecthidrosililación
dc.subjectIniciación por radicales Paso
dc.subjectEnlaces múltiples
dc.titleHydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step
dc.typeArtículos de revistas


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