dc.creator | Lapuh, María Ivana | |
dc.creator | Dana, Alejandro Leonel | |
dc.creator | Di Chenna, Pablo Hector | |
dc.creator | Darses, Benjamin | |
dc.creator | Duran, Fernando Javier | |
dc.creator | Dauban, Philippe | |
dc.date.accessioned | 2021-01-21T15:10:07Z | |
dc.date.accessioned | 2022-10-15T16:38:37Z | |
dc.date.available | 2021-01-21T15:10:07Z | |
dc.date.available | 2022-10-15T16:38:37Z | |
dc.date.created | 2021-01-21T15:10:07Z | |
dc.date.issued | 2019-04 | |
dc.identifier | Lapuh, María Ivana; Dana, Alejandro Leonel; Di Chenna, Pablo Hector; Darses, Benjamin; Duran, Fernando Javier; et al.; Late-stage C–H amination of abietane diterpenoids; Royal Society of Chemistry; Organic & Biomolecular Chemistry; 17; 19; 4-2019; 4736-4746 | |
dc.identifier | 1477-0520 | |
dc.identifier | http://hdl.handle.net/11336/123301 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4410276 | |
dc.description.abstract | This study aims at highlighting the synthetic versatility of the rhodium-catalyzed C-H amination reactions using iodine(iii) oxidants for the late-stage functionalization of natural products. Inter-and intramolecular nitrene insertions have been performed from various abietane diterpenoids, leading to the amination of the C-3, C-6, C-7, C-11 and C-15 positions. Ca. 20 aminated compounds have been isolated with yields of up to 86% and high levels of regio-, chemo-and stereoselectivities. | |
dc.language | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C9OB00272C | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/c9ob00272c | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.subject | AMINACION C-H | |
dc.subject | DITERPENES | |
dc.subject | DIFLUOROMETILO | |
dc.subject | SINTESIS ORGANICA | |
dc.title | Late-stage C–H amination of abietane diterpenoids | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:ar-repo/semantics/artículo | |
dc.type | info:eu-repo/semantics/publishedVersion | |