Generalized statistical description of adsorption of polyatomics

dc.creatorRiccardo, Jose Luis
dc.creatorRomá, Federico José
dc.creatorRamirez Pastor, Antonio Jose
dc.date.accessioned2022-05-27T12:47:09Z
dc.date.accessioned2022-10-15T13:46:19Z
dc.date.available2022-05-27T12:47:09Z
dc.date.available2022-10-15T13:46:19Z
dc.date.created2022-05-27T12:47:09Z
dc.date.issued2005-12
dc.identifierRiccardo, Jose Luis; Romá, Federico José; Ramirez Pastor, Antonio Jose; Generalized statistical description of adsorption of polyatomics; Elsevier Science; Applied Surface Science; 252; 3; 12-2005; 505-511
dc.identifier0169-4332
dc.identifierhttp://hdl.handle.net/11336/158338
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4393051
dc.description.abstractMultisite-occupancy adsorption is described as a fractional statistic problem, based on Haldane’s statistics. Site exclusion is characterized by a statistical exclusion parameter, g, which relates to the molecular size and lattice geometry. A general adsorption isotherm is obtained and comparisons with experiments indicate that the spatial configuration of adsorbed molecules and lateral interactions may accurately be assessed from this theory. In addition, the theoretical framework developed in this paper allows to describe orientational transitions occurring in adlayers of polyatomics.
dc.languageeng
dc.publisherElsevier Science
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apsusc.2005.02.067
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0169433205003028
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectADSORPTION ISOTHERMS
dc.subjectMULTISITE OCCUPANCY
dc.subjectQUANTUM FRACTIONAL STATISTICS
dc.subjectMONTE CARLO SIMULATIONS
dc.subjectEQUILIBRIUM THERMODYNAMICS AND STATISTICAL MECHANICS
dc.titleGeneralized statistical description of adsorption of polyatomics
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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