dc.creator | Diaz Duran, Ana Katherine | |
dc.creator | Viva, Federico Andres | |
dc.creator | Roncaroli, Federico | |
dc.date.accessioned | 2021-01-28T12:03:02Z | |
dc.date.accessioned | 2022-10-15T09:31:08Z | |
dc.date.available | 2021-01-28T12:03:02Z | |
dc.date.available | 2022-10-15T09:31:08Z | |
dc.date.created | 2021-01-28T12:03:02Z | |
dc.date.issued | 2019-10 | |
dc.identifier | Diaz Duran, Ana Katherine; Viva, Federico Andres; Roncaroli, Federico; High durability fuel cell cathodes obtained from cobalt metal organic frameworks; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 320; 10-2019; 1-8 | |
dc.identifier | 0013-4686 | |
dc.identifier | http://hdl.handle.net/11336/124005 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4370646 | |
dc.description.abstract | Mesoporous carbons doped with Nitrogen and Cobalt were obtained from the pyrolysis of two different Cobalt Metal-Organic Frameworks (MOFs, ZIF-67 and CoNic) and from one linear coordination polymer (CP, Co(CO2)2Pz). (ZIF-67 = catena-(bis(μ2-2-methylimidazolato)-cobalt(II), CoNic = catena-(bis(μ3-nicotinato)-bis(μ2-nicotinato)-(μ2-aqua)-di-cobalt(II), Co(CO2)2Pz = catena-((μ2-pyrazine-2,3-dicarboxylato)-diaqua-cobalt(II) dehydrate). The carbonization products were evaluated as cathode catalysts in polymer electrolyte membrane fuel cell (PEMFC). Membrane Electrode Assemblies (MEAs) prepared with the Co–N doped carbons and Pt 20% supported on Vulcan carbon as anode catalyst, were characterized in a PEMFC and post mortem by SEM, EDX, XPS and X-ray diffraction. The best catalyst was the one derived from the Co(CO2)2Pz polymer, pyrolyzed at 700 °C and acid leached. It reached a maximum power density of 259 mW cm−2, a limiting current of 1.36 A cm−2 and an open cell voltage of 0.86 V. These parameters are comparable to those of Pt 20% on Vulcan. The fuel cell prototype constructed with the Co(CO2)2Pz 700 °C material was able to operate for 500 h, without significant change of its electrochemical parameters and without leaking Co or Pt. | |
dc.language | eng | |
dc.publisher | Pergamon-Elsevier Science Ltd | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0013468619314719 | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.electacta.2019.134623 | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.subject | COORDINATION POLYMER | |
dc.subject | FUEL CELL | |
dc.subject | METAL ORGANIC FRAMEWORK | |
dc.subject | NON-NOBLE CATALYST | |
dc.subject | PLATINUM-FREE | |
dc.subject | POLYMER ELECTROLYTE MEMBRANE | |
dc.title | High durability fuel cell cathodes obtained from cobalt metal organic frameworks | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:ar-repo/semantics/artículo | |
dc.type | info:eu-repo/semantics/publishedVersion | |