Effect of the support on the selective hydrogenation of benzeneover ruthenium catalysts. 1. Al2O3 and SiO2

dc.creatorMazzieri, Vanina Alejandra
dc.creatorFígoli, Nora
dc.creatorPascual, Fernando-Coloma
dc.creatorL'Argentière, Pablo
dc.date.accessioned2019-06-12T11:31:53Z
dc.date.accessioned2022-10-15T08:56:02Z
dc.date.available2019-06-12T11:31:53Z
dc.date.available2022-10-15T08:56:02Z
dc.date.created2019-06-12T11:31:53Z
dc.date.issued2005-07
dc.identifierMazzieri, Vanina Alejandra; Fígoli, Nora; Pascual, Fernando-Coloma; L'Argentière, Pablo; Effect of the support on the selective hydrogenation of benzeneover ruthenium catalysts. 1. Al2O3 and SiO2; Springer; Catalysis Letters; 102; 1-2; 7-2005; 79-82
dc.identifier1011-372X
dc.identifierhttp://hdl.handle.net/11336/78023
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4367571
dc.description.abstractThe effect of the support on the liquid phase selective hydrogenation of benzene to cyclohexene over Ru catalysts was studied. Catalysts were prepared using RuCl3 as precursor and characterized by hydrogen chemisorption, XPS and TPR. The reaction was carried out at 373 K and 2 MPa using a stirred tank reactor. It was found that the catalytic activity is not influenced by the Ru dispersion. More electron-deficient Ru species are present on Al 2O3 than on SiO2. The electronic state of Ru affects the selectivity to cyclohexene.
dc.languageeng
dc.publisherSpringer
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s10562-005-5206-6
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectCYCLOHEXENE
dc.subjectEFFECT OF THE SUPPORT
dc.subjectRU CATALYSTS
dc.subjectSELECTIVE HYDROGENATION
dc.titleEffect of the support on the selective hydrogenation of benzeneover ruthenium catalysts. 1. Al2O3 and SiO2
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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