Exact statistical thermodynamics of alkane binary mixtures in zeolites: New interpretation of the adsorption preference reversal phenomenon from multisite-occupancy theory

dc.creatorDavila, Mara Veronica
dc.creatorRiccardo, Jose Luis
dc.creatorRamirez Pastor, Antonio Jose
dc.date.accessioned2021-02-17T13:14:39Z
dc.date.accessioned2022-10-15T08:03:09Z
dc.date.available2021-02-17T13:14:39Z
dc.date.available2022-10-15T08:03:09Z
dc.date.created2021-02-17T13:14:39Z
dc.date.issued2009-08-06
dc.identifierDavila, Mara Veronica; Riccardo, Jose Luis; Ramirez Pastor, Antonio Jose; Exact statistical thermodynamics of alkane binary mixtures in zeolites: New interpretation of the adsorption preference reversal phenomenon from multisite-occupancy theory; Elsevier Science; Chemical Physics Letters; 477; 4-6; 6-8-2009; 402-405
dc.identifier0009-2614
dc.identifierhttp://hdl.handle.net/11336/125775
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4363350
dc.description.abstractThe rigorous statistical thermodynamics of mixtures of polyatomic species adsorbed on one-dimensional substrates is presented. The thermodynamic functions calculated for a monomer-dimer mixture are applied to describe the adsorption of methane-ethane mixtures in zeolites. The theoretical formalism reproduces the main features of the system, showing that the displacement of ethane by methane at higher pressures, a phenomenon known as Adsorption Preference Reversal, is the result of the difference of size (or number of occupied sites) between the adsorbed species.
dc.languageeng
dc.publisherElsevier Science
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0009261409008379
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cplett.2009.07.031
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectALKANE
dc.subjectADSORPTION
dc.subjectMIXTURE
dc.subjectREVERSAL
dc.titleExact statistical thermodynamics of alkane binary mixtures in zeolites: New interpretation of the adsorption preference reversal phenomenon from multisite-occupancy theory
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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