Facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes

dc.creatorZanotto, Franco Martín
dc.creatorFernández, Ricardo Ariel
dc.creatorDassie, Sergio Alberto
dc.date.accessioned2018-11-15T15:21:11Z
dc.date.accessioned2022-10-15T07:44:21Z
dc.date.available2018-11-15T15:21:11Z
dc.date.available2022-10-15T07:44:21Z
dc.date.created2018-11-15T15:21:11Z
dc.date.issued2017-12
dc.identifierZanotto, Franco Martín; Fernández, Ricardo Ariel; Dassie, Sergio Alberto; Facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 258; 12-2017; 727-734
dc.identifier0013-4686
dc.identifierhttp://hdl.handle.net/11336/64532
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4361827
dc.description.abstractThe theory of cyclic voltammetry of facilitated proton transfer-electron transfer coupled reactions (FPT-ET reactions) in a thick organic film modified electrode is developed. It is shown that the coupling between the facilitated proton transfer-electron transfer processes has a marked effect on the shape of the current-potential profiles. The model allows the analysis of the system in different experimental conditions, such as pH and concentration ratios between the redox probe and the transferring protonated species. This model for proton transfer assisted by different neutral weak bases in a two polarized interfaces system is compared to our previous results for a single polarizable interface. Finally, considerations regarding the application of the thick-film setup are discussed.
dc.languageeng
dc.publisherPergamon-Elsevier Science Ltd
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0013468617324817
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.electacta.2017.11.119
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectFACILITATED PROTON TRANSFER
dc.subjectION TRANSFER-ELECTRON TRANSFER COUPLED REACTIONS
dc.subjectPROTONATABLE SPECIES TRANSFER
dc.subjectTHICK-FILM MODIFIED ELECTRODES
dc.titleFacilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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