Water-soluble N-heterocyclic carbene platinum(0) complexes: Recyclable catalysts for the hydrosilylation of alkynes in water at room temperature

dc.creatorSilbestri, Gustavo Fabián
dc.creatorFlores, Juan Carlos
dc.creatorDe Jesús, Ernesto
dc.date.accessioned2018-11-07T20:19:57Z
dc.date.accessioned2022-10-15T07:13:02Z
dc.date.available2018-11-07T20:19:57Z
dc.date.available2022-10-15T07:13:02Z
dc.date.created2018-11-07T20:19:57Z
dc.date.issued2012-04
dc.identifierSilbestri, Gustavo Fabián; Flores, Juan Carlos; De Jesús, Ernesto; Water-soluble N-heterocyclic carbene platinum(0) complexes: Recyclable catalysts for the hydrosilylation of alkynes in water at room temperature; American Chemical Society; Organometallics; 31; 8; 4-2012; 3355-3360
dc.identifier0276-7333
dc.identifierhttp://hdl.handle.net/11336/63937
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4359190
dc.description.abstractThe synthesis and characterization of new water-soluble platinum(0) complexes bearing sulfonated N-heterocyclic carbene (NHC) and divinyltetramethylsiloxane (dvtms) ligands are described. These complexes, of the general formula (NHC)Pt(dvtms), are active and recyclable catalysts for the hydrosilylation of phenylacetylene and other alkynes at room temperature in water. Our findings indicate that the NHC-Pt(0) bonds are reasonably stable under these catalytic conditions, although hydrolysis is observed at temperatures above 80 °C in pure water. © 2012 American Chemical Society.
dc.languageeng
dc.publisherAmerican Chemical Society
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/om300148q
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/om300148q
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectN-HETEROCYCLIC CARBENE
dc.subjectRECYCLABLE CATALYSTS
dc.subjectHYDROSILYLATION
dc.titleWater-soluble N-heterocyclic carbene platinum(0) complexes: Recyclable catalysts for the hydrosilylation of alkynes in water at room temperature
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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