dc.creator | Ricci, Alejandra Marcela | |
dc.creator | Calvo, Ernesto Julio | |
dc.creator | Martin, Santiago | |
dc.creator | Nichols, Richard J. | |
dc.date.accessioned | 2019-03-18T21:01:55Z | |
dc.date.accessioned | 2022-10-15T04:56:33Z | |
dc.date.available | 2019-03-18T21:01:55Z | |
dc.date.available | 2022-10-15T04:56:33Z | |
dc.date.created | 2019-03-18T21:01:55Z | |
dc.date.issued | 2010-02 | |
dc.identifier | Ricci, Alejandra Marcela; Calvo, Ernesto Julio; Martin, Santiago; Nichols, Richard J.; Electrochemical scanning tunneling spectroscopy of redox-active molecules bound by Au-C bonds; American Chemical Society; Journal of the American Chemical Society; 132; 8; 2-2010; 2494-2495 | |
dc.identifier | 0002-7863 | |
dc.identifier | http://hdl.handle.net/11336/71954 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4347224 | |
dc.description.abstract | (Figure Presented) A comparison of the electrochemical gating of molecular conduction by a redox [Os(bipyridine)(pyridine)Cl] complex tethered to Au(111) with two different metal-molecule junctions in a scanning tunneling microscope nanogap is presented. The same redox molecular structure was tethered by mercaptobenzoic acid or reduction of the aryldiazonium salt of p-aminobenzoic acid, resulting in a Au-S or Au-C bond, respectively. A two-step electron-transfer mechanism with vibrational relaxation of the redox molecule is apparent in each case. Copyright © 2009 American Chemical Society. | |
dc.language | eng | |
dc.publisher | American Chemical Society | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/ja907867b | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/full/10.1021/ja907867b | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.subject | Electrochemical | |
dc.subject | Molecular electronics | |
dc.subject | Scanning Tunelling spectroscopy | |
dc.subject | Osmium | |
dc.title | Electrochemical scanning tunneling spectroscopy of redox-active molecules bound by Au-C bonds | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:ar-repo/semantics/artículo | |
dc.type | info:eu-repo/semantics/publishedVersion | |