dc.creator | Glembockyte, Viktorija | |
dc.creator | Frenette, Mathieu | |
dc.creator | Mottillo, Cristina | |
dc.creator | Durantini, Andres Matías | |
dc.creator | Gostick, Jeff | |
dc.creator | Strukil, Vjekoslav | |
dc.creator | Friščić, Tomislav | |
dc.creator | Cosa, Gonzalo | |
dc.date.accessioned | 2022-05-19T20:54:40Z | |
dc.date.accessioned | 2022-10-15T04:45:33Z | |
dc.date.available | 2022-05-19T20:54:40Z | |
dc.date.available | 2022-10-15T04:45:33Z | |
dc.date.created | 2022-05-19T20:54:40Z | |
dc.date.issued | 2018-11-21 | |
dc.identifier | Glembockyte, Viktorija; Frenette, Mathieu; Mottillo, Cristina; Durantini, Andres Matías; Gostick, Jeff; et al.; Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal–Organic Framework; American Chemical Society; Journal of the American Chemical Society; 140; 49; 21-11-2018; 16882-16887 | |
dc.identifier | 0002-7863 | |
dc.identifier | http://hdl.handle.net/11336/157862 | |
dc.identifier | 1520-5126 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4346397 | |
dc.description.abstract | We report a strategy to synthesize highly emissive, photostable, microporous materials by solid-state entrapment of boron dipyrromethene (BODIPY) fluorophores in a metal–organic framework. Solvent-free mechanochemistry or accelerated aging enabled quantitative capture and dispersal of the PM605 dye within the ZIF-8 framework starting from inexpensive, commercial materials. While the design of emissive BODIPY solids is normally challenged by quenching in a densely packed environment, herein reported PM605@ZIF-8 materials show excellent emissive properties and to the best of our knowledge an unprecedented ∼10-fold enhancement of BODIPY photostability. Time-resolved and steady-state fluorescence studies of PM605@ZIF-8 show that interchromophore interactions are minimal at low dye loadings, but at higher ones lead to through-pore energy transfer between chromophores and to aggregate species. | |
dc.language | eng | |
dc.publisher | American Chemical Society | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jacs.8b09608 | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/jacs.8b09608 | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.subject | BODIPY | |
dc.title | Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal–Organic Framework | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:ar-repo/semantics/artículo | |
dc.type | info:eu-repo/semantics/publishedVersion | |