The non-metathetic role of Grubbs’ carbene complexes: From hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction

dc.creatorPoeylaut Palena, Andrés Alberto
dc.creatorTestero, Sebastian Andres
dc.creatorMata, Ernesto Gabino
dc.date.accessioned2021-03-11T15:31:15Z
dc.date.accessioned2022-10-15T03:41:31Z
dc.date.available2021-03-11T15:31:15Z
dc.date.available2022-10-15T03:41:31Z
dc.date.created2021-03-11T15:31:15Z
dc.date.issued2011-02
dc.identifierPoeylaut Palena, Andrés Alberto; Testero, Sebastian Andres; Mata, Ernesto Gabino; The non-metathetic role of Grubbs’ carbene complexes: From hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction; Royal Society of Chemistry; Chemical Communications; 47; 5; 2-2011; 1565-1567
dc.identifier1359-7345
dc.identifierhttp://hdl.handle.net/11336/128082
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4341189
dc.description.abstractAn efficient and high-yielding “hydrogen-free” reduction of α,β-unsaturated alkenes was carried out employing Grubbs' catalyst in a non-metathetic role and Et3SiH. Conditions were optimized under microwave irradiation. Application to the solid-phase organic synthesis allows a facile construction of sp3–sp3 carbon bonds through a sequential cross metathesis/olefin reduction.
dc.languageeng
dc.publisherRoyal Society of Chemistry
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2011/cc/c0cc04115g#!divAbstract
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/C0CC04115G
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjecthydrogen free-reduction
dc.subjectGrubbs catalyst
dc.subjectsequential cross-metathesis/reduction
dc.subjectSolid Phase
dc.titleThe non-metathetic role of Grubbs’ carbene complexes: From hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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