The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction

dc.creatorMontero, María de Los Angeles
dc.creatorMarozzi, Carlos Alberto
dc.creatorGennero, Maria Rosa
dc.creatorChialvo, Abel Cesar
dc.date.accessioned2020-09-16T13:52:26Z
dc.date.accessioned2022-10-15T01:58:18Z
dc.date.available2020-09-16T13:52:26Z
dc.date.available2022-10-15T01:58:18Z
dc.date.created2020-09-16T13:52:26Z
dc.date.issued2007-12
dc.identifierMontero, María de Los Angeles; Marozzi, Carlos Alberto; Gennero, Maria Rosa; Chialvo, Abel Cesar; The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 52; 5; 12-2007; 2083-2090
dc.identifier0013-4686
dc.identifierhttp://hdl.handle.net/11336/114093
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4332671
dc.description.abstractAn alternative method for the determination of the kinetic parameters involved in the elementary steps of the reaction mechanism of the hydrogen electrode reaction is proposed. It is based on the determination of the variation of the polarization resistance in a tubular platinum electrode with a laminar flow of electrolyte as a function of the activity of protons of the electrolyte solution. A theoretical expression that relates the experimental variables and the equilibrium polarization resistance is developed, which takes into account the current distribution along the electrode surface. The results are compared with others obtained previously, contributing to the verification of the kinetic mechanism through a completely different experimental procedure.
dc.languageeng
dc.publisherPergamon-Elsevier Science Ltd
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.electacta.2006.08.017
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectHYDROGEN ELECTRODE REACTION
dc.subjectKINETIC PARAMETERS
dc.subjectPLATINUM
dc.subjectPOLARIZATION RESISTANCE
dc.subjectTUBULAR ELECTRODE
dc.titleThe evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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