Three Redox States of Nitrosyl: NO+, NO., and NO-/HNO Interconvert Reversibly on the Same Pentacyanoferrate(II) Platform

dc.creatorMontenegro, Andrea Constanza
dc.creatorAmorebieta, Valentín Tomás
dc.creatorSlep, Leonardo Daniel
dc.creatorMartín, Diego Federico
dc.creatorRoncaroli, Federico
dc.creatorMurgida, Daniel Horacio
dc.creatorBari, Sara Elizabeth
dc.creatorOlabe Iparraguirre, Jose Antonio
dc.date.accessioned2019-03-25T21:20:52Z
dc.date.accessioned2022-10-15T00:55:57Z
dc.date.available2019-03-25T21:20:52Z
dc.date.available2022-10-15T00:55:57Z
dc.date.created2019-03-25T21:20:52Z
dc.date.issued2009-05
dc.identifierMontenegro, Andrea Constanza; Amorebieta, Valentín Tomás; Slep, Leonardo Daniel; Martín, Diego Federico; Roncaroli, Federico; et al.; Three Redox States of Nitrosyl: NO+, NO., and NO-/HNO Interconvert Reversibly on the Same Pentacyanoferrate(II) Platform; Wiley VCH Verlag; Angewandte Chemie; 48; 23; 5-2009; 4213-4216
dc.identifier1433-7851
dc.identifierhttp://hdl.handle.net/11336/72489
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4327254
dc.description.abstractNot so elusive: [FeII(CN)5(HNO)]3- has been characterized spectroscopically after the two-electron reduction of nitroprusside (see scheme). The complex is stable at pH 6, slowly decomposing to [Fe(CN)6]4- and N2O. It is deprotonated at increasing pH value with oxidation of bound NO- to [Fe II(CN)5(NO)]3-. [FeII(CN) 5 (HNO)]3- is the first non-heme iron-nitroxyl complex prepared in aqueous solution that is reversibly redox-active under biologically relevant conditions. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
dc.languageeng
dc.publisherWiley VCH Verlag
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200806229
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/anie.200806229
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectCYANIDES
dc.subjectIRON
dc.subjectNITROGEN OXIDES
dc.subjectNITROXYL COMPLEX
dc.subjectREDOX CHEMISTRY
dc.titleThree Redox States of Nitrosyl: NO+, NO., and NO-/HNO Interconvert Reversibly on the Same Pentacyanoferrate(II) Platform
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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