Facilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases

dc.creatorVega Mercado, Franco
dc.creatorOvejero, Juan Manuel
dc.creatorZanotto, Franco Martín
dc.creatorSerial, María Raquel
dc.creatorVelasco, Manuel Isaac
dc.creatorFernández, Ricardo Ariel
dc.creatorAcosta, Rodolfo Héctor
dc.creatorDassie, Sergio Alberto
dc.date.accessioned2018-11-15T17:54:02Z
dc.date.accessioned2022-10-15T00:54:35Z
dc.date.available2018-11-15T17:54:02Z
dc.date.available2022-10-15T00:54:35Z
dc.date.created2018-11-15T17:54:02Z
dc.date.issued2017-04
dc.identifierVega Mercado, Franco; Ovejero, Juan Manuel; Zanotto, Franco Martín; Serial, María Raquel; Velasco, Manuel Isaac; et al.; Facilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases; Elsevier Science Sa; Journal of Electroanalytical Chemistry; 791; 4-2017; 64-74
dc.identifier1572-6657
dc.identifierhttp://hdl.handle.net/11336/64554
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4327123
dc.description.abstractA novel quantitative methodology to determine the partition coefficients of neutral weak bases is developed. This new electrochemical approach is based on the measurement of the total transferred charge across the oil | water interface under forced hydrodynamic conditions. The complete procedure has been validated by computational simulations and experimental results (Tylosin A). In addition, flow pattern caused inside the electrochemical cell was simulated with computational fluid dynamics using finite element methods and correlated with experimental results obtained by magnetic resonance imaging.
dc.languageeng
dc.publisherElsevier Science Sa
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.jelechem.2017.03.005
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S1572665717301546
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectFACILITATED PROTON TRANSFER
dc.subjectFINITE ELEMENT METHOD
dc.subjectFORCED HYDRODYNAMIC CONDITIONS
dc.subjectLIQUID | LIQUID INTERFACE
dc.subjectMAGNETIC RESONANCE IMAGING
dc.subjectPARTITION COEFFICIENT
dc.titleFacilitated proton transfer across liquid | liquid interfaces under forced hydrodynamic conditions. Determination of partition coefficients of neutral weak bases
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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