| dc.creator | Ciolino, Andrés Eduardo | |
| dc.creator | Pieroni, Olga Inés | |
| dc.creator | Vuano, Bruno Mario | |
| dc.creator | Villar, Marcelo Armando | |
| dc.creator | Valles, Enrique Marcelo | |
| dc.date.accessioned | 2020-03-13T22:55:36Z | |
| dc.date.accessioned | 2022-10-15T00:32:59Z | |
| dc.date.available | 2020-03-13T22:55:36Z | |
| dc.date.available | 2022-10-15T00:32:59Z | |
| dc.date.created | 2020-03-13T22:55:36Z | |
| dc.date.issued | 2004-06 | |
| dc.identifier | Ciolino, Andrés Eduardo; Pieroni, Olga Inés; Vuano, Bruno Mario; Villar, Marcelo Armando; Valles, Enrique Marcelo; Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions; John Wiley & Sons Inc; Journal of Polymer Science Part A: Polymer Chemistry; 42; 12; 6-2004; 2920-2930 | |
| dc.identifier | 0887-624X | |
| dc.identifier | http://hdl.handle.net/11336/99619 | |
| dc.identifier | CONICET Digital | |
| dc.identifier | CONICET | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4325190 | |
| dc.description.abstract | We report preliminary results for the synthesis of poly(ethylene)-graft-poly(dimethylsiloxane) copolymers (PE-g-PDMS) obtained by catalytic hydrogenation of poly(butadiene)-graft-poly(dimethylsiloxane) copolymers (PB-g-PDMS). These last copolymers were synthesized by hydrosilylation reactions between commercial poly(butadiene) (PB) and w-silane poly(dimethylsiloxane). The reaction was carried in solution catalyzed by cis-dichloro bis(diethylsufide) platinum (II) salt (Cl2[S(CH2CH3)2]Pt). The PB-g-PDMS copolymers were analyzed by 1H- and 13C-NMR spectroscopy and the relative weight percentages (wt%) of the grafted poly(dimethylsiloxane) macromonomer were determined from the integrated peak areas of the spectra. | |
| dc.language | eng | |
| dc.publisher | John Wiley & Sons Inc | |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/pola.20032 | |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1002/pola.20032 | |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | poly(ethylene)-graft-poly(dimethylsiloxane) | |
| dc.subject | hydrogenation | |
| dc.subject | hydrosilylation reactions | |
| dc.subject | 1H- and 13C-NMR | |
| dc.title | Synthesis of poly(butadiene)-graf-poly(dimethylsiloxane) and poly(ethylene)-graft-poly(dimethylsiloxane) copolymers using hydrosilylation reactions | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:ar-repo/semantics/artículo | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
