Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers

dc.creatorChen, N.
dc.creatorLee, N.
dc.creatorBortolato, Santiago Andres
dc.creatorMartino, D. M.
dc.date.accessioned2019-10-23T19:56:33Z
dc.date.accessioned2022-10-14T23:27:39Z
dc.date.available2019-10-23T19:56:33Z
dc.date.available2022-10-14T23:27:39Z
dc.date.created2019-10-23T19:56:33Z
dc.date.issued2018-10
dc.identifierChen, N.; Lee, N.; Bortolato, Santiago Andres; Martino, D. M.; Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers; Taylor & Francis; Green Chemistry Letters and Reviews; 11; 4; 10-2018; 387-398
dc.identifier1751-8253
dc.identifierhttp://hdl.handle.net/11336/87156
dc.identifier1751-7192
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4319370
dc.description.abstractPolymer curing is a complex process that significantly delineate the final properties of the synthetized material. In this work, the photo-induced crosslinking reaction of synthetic “bioinspired” copolymers based on thymine and ionic groups was studied by gel permeation chromatography and UV absorption spectroscopy. A mathematical model for the curing process based on statistical techniques and coupled to the kinetics of crosslinking was developed. The model allows to predict both, the evolution of the crosslinking degree as a function of curing time and the gel times as a function of the molecular structure of the copolymer and the curing conditions. The theoretical values showed a very good agreement with the UV-Vis and GPC spectroscopy experimental results for all the copolymers studied. A better knowledge of the curing kinetics of thymine-based biopolymers will enable to develop materials with pre-specified properties and to improve their applications.
dc.languageeng
dc.publisherTaylor & Francis
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/full/10.1080/17518253.2018.1516809
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1080/17518253.2018.1516809
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCURING KINETICS
dc.subjectMATHEMATICAL MODELING
dc.subjectTHYMINE COPOLYMERS
dc.titleExperimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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