| dc.creator | Robert-Peillard, Fabien | |
| dc.creator | Di Chenna, Pablo Hector | |
| dc.creator | Liang, Chungen | |
| dc.creator | Lescot, Camille | |
| dc.creator | Collet, Florence | |
| dc.creator | Dodd, Robert H. | |
| dc.creator | Dauban, Philippe | |
| dc.date.accessioned | 2019-02-04T21:26:51Z | |
| dc.date.accessioned | 2022-10-14T23:20:55Z | |
| dc.date.available | 2019-02-04T21:26:51Z | |
| dc.date.available | 2022-10-14T23:20:55Z | |
| dc.date.created | 2019-02-04T21:26:51Z | |
| dc.date.issued | 2010-06 | |
| dc.identifier | Robert-Peillard, Fabien; Di Chenna, Pablo Hector; Liang, Chungen; Lescot, Camille; Collet, Florence; et al.; Catalytic stereoselective alkene aziridination with sulfonimidamides; Pergamon-Elsevier Science Ltd; Tetrahedron: Asymmetry; 21; 11-12; 6-2010; 1447-1457 | |
| dc.identifier | 0957-4166 | |
| dc.identifier | http://hdl.handle.net/11336/69386 | |
| dc.identifier | CONICET Digital | |
| dc.identifier | CONICET | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4318806 | |
| dc.description.abstract | Diastereoselective copper-catalyzed alkene aziridination has been investigated using chiral nitrenes generated from sulfonimidamides in the presence of an iodine(III) oxidant. Starting from a stoichiometric amount of the substrates, the corresponding aziridines were isolated with excellent yields of up to 96%. Good levels of asymmetric induction were obtained in the case of electron-poor olefins, with an optimal de of 94% being reached starting from tert-butyl acrylate. Matching and mismatching effects were also observed upon the use of chiral copper catalysts for the aziridination of styrene. | |
| dc.language | eng | |
| dc.publisher | Pergamon-Elsevier Science Ltd | |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0957416610001874 | |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.tetasy.2010.03.032 | |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
| dc.rights | info:eu-repo/semantics/restrictedAccess | |
| dc.subject | AZIRIDINE | |
| dc.subject | ALKENE | |
| dc.subject | NITRENE | |
| dc.subject | COPPER | |
| dc.subject | HYPERVALENT IODINE | |
| dc.subject | STEREOSELECTIVITY | |
| dc.title | Catalytic stereoselective alkene aziridination with sulfonimidamides | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:ar-repo/semantics/artículo | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
