Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient

dc.creatorKilo, Martin
dc.creatorTaylor, Marcela Andrea
dc.creatorArgirusis, Christos
dc.creatorBorchardt, Günter
dc.creatorWeber, Sylvain
dc.creatorScherrer, Hubert
dc.creatorJackson, Robert A.
dc.date.accessioned2019-04-15T14:05:56Z
dc.date.accessioned2022-10-14T22:09:48Z
dc.date.available2019-04-15T14:05:56Z
dc.date.available2022-10-14T22:09:48Z
dc.date.created2019-04-15T14:05:56Z
dc.date.issued2004-06
dc.identifierKilo, Martin; Taylor, Marcela Andrea; Argirusis, Christos; Borchardt, Günter; Weber, Sylvain; et al.; Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient; American Institute of Physics; Journal of Chemical Physics; 121; 11; 6-2004; 5482-5487
dc.identifier0021-9606
dc.identifierhttp://hdl.handle.net/11336/74365
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/4312331
dc.description.abstractThe diffusion of all stable lanthanides in calcia stabilized zirconia (CSZ) and in yttria stabilized zirconia (YSZ) was measured. Lanthanide migration enthalpies were calculated using the Mott-littleton approach. The results suggest that the bulk diffusion coefficient depends on the ionic radius of the lanthanide tracer. It was also found that the experimental activation enthalpies are about 6eV for CSZ and between 4 and 5 eV for YSZ and almost constant for all lanthanides.
dc.languageeng
dc.publisherAmerican Institute of Physics
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1063/1.1784439
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.1784439
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectLanthanides
dc.subjectCation diffusion
dc.titleLanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.typeinfo:eu-repo/semantics/publishedVersion


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