Argentina
| info:eu-repo/semantics/article
Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions
dc.creator | Dennehy, Mariana | |
dc.creator | Amo Ochoa, Pilar | |
dc.creator | Freire Espeleta, Eleonora | |
dc.creator | Suarez, Sebastian | |
dc.creator | Halac, Emilia | |
dc.creator | Baggio, Ricardo | |
dc.date.accessioned | 2020-01-14T19:11:57Z | |
dc.date.accessioned | 2022-10-14T22:05:51Z | |
dc.date.available | 2020-01-14T19:11:57Z | |
dc.date.available | 2022-10-14T22:05:51Z | |
dc.date.created | 2020-01-14T19:11:57Z | |
dc.date.issued | 2018-02 | |
dc.identifier | Dennehy, Mariana; Amo Ochoa, Pilar; Freire Espeleta, Eleonora; Suarez, Sebastian; Halac, Emilia; et al.; Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 74; 2; 2-2018; 186-193 | |
dc.identifier | 0108-2701 | |
dc.identifier | http://hdl.handle.net/11336/94647 | |
dc.identifier | 2053-2296 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/4311975 | |
dc.description.abstract | Among the potential applications of coordination polymers, electrical conductivity ranks high in technological interest. We report the synthesis, crystal structure and spectroscopic analysis of an AgI–thiosaccharinate one-dimensional coordination polymer {systematic name: catena-poly[[[aquatetrakis(μ3-1,1-dioxo-1,2-benzisothiazole-3-thiolato-κ3N:S3:S3)tetrasilver(I)]-μ2-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N′] dimethyl sulfoxide hemisolvate]}, {[Ag4(C7H4NO2S2)4(C13H14N2)(H2O)]·0.5C2H6OS}n, with the 4,4′-(propane-1,3-diyl)dipyridine ligand acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag...Ag distance of 2.8306 (9) Å, well within the range of argentophilic interactions, confirmed experimentally as such by a Raman study on the low-frequency spectrum, and corroborated theoretically by an Atoms in Molecules (AIM) analysis of the calculated electron density. Electrical conductivity measurements show that this complex can act as a semiconductor with moderate conductivity. | |
dc.language | eng | |
dc.publisher | Wiley Blackwell Publishing, Inc | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229618000128 | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1107/S2053229618000128 | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.subject | SILVER(I) | |
dc.subject | POLYMERIC STRUCTURE | |
dc.subject | LOW CONDUCTIVITY | |
dc.subject | ARGENTOPHILIC | |
dc.subject | ELECTRICAL PROPERTIES | |
dc.subject | CRYSTAL STRUCTURE. | |
dc.subject | COORDINATION POLYMER | |
dc.subject | SILVER(I) | |
dc.title | Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions | |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:ar-repo/semantics/artículo | |
dc.type | info:eu-repo/semantics/publishedVersion |