Stereoselective Nucleophilic Addition of Potassium Alkyltrifluoroborates to Cyclic N-Acyliminium Ions: a Simple and Mild Approach to Chiral 5-Alkyl-pyrrolidin-2-ones

dc.contributorUniversidade de São Paulo (USP)
dc.contributorUniversidade Federal de São Paulo (UNIFESP)
dc.creatorVieira, Adriano S.
dc.creatorFerreira, Fernando P. [UNIFESP]
dc.creatorGuarezemini, Alexandre S.
dc.creatorStefani, Helio A. [UNIFESP]
dc.date.accessioned2016-01-24T13:52:05Z
dc.date.accessioned2022-10-07T20:52:41Z
dc.date.available2016-01-24T13:52:05Z
dc.date.available2022-10-07T20:52:41Z
dc.date.created2016-01-24T13:52:05Z
dc.date.issued2009-01-01
dc.identifierAustralian Journal of Chemistry. Collingwood: Csiro Publishing, v. 62, n. 8, p. 909-916, 2009.
dc.identifier0004-9425
dc.identifierhttp://repositorio.unifesp.br/handle/11600/31180
dc.identifier10.1071/CH09067
dc.identifierWOS:000268955500020
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/4024176
dc.description.abstractThe stereoselective nucleophilic addition of potassium alkyltrifluoroborates to cyclic N-acyliminium ions derived from N-benzyl-3,4,5-triacetoxy-pyrrolidin-2-one, which affords 5-substituted-pyrrolidin-2-ones, is described. the products are obtained in moderate to good yields and are produced predominantly as the anti diastereomer.
dc.languageeng
dc.publisherCsiro Publishing
dc.relationAustralian Journal of Chemistry
dc.rightsAcesso restrito
dc.titleStereoselective Nucleophilic Addition of Potassium Alkyltrifluoroborates to Cyclic N-Acyliminium Ions: a Simple and Mild Approach to Chiral 5-Alkyl-pyrrolidin-2-ones
dc.typeArtigo


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