masterThesis
Avaliação físico-química e quimiométrica de combustível aeronáutico: uma abordagem acerca da estabilidade após estocagem e com adição de adulterantes
Fecha
2021-12-27Registro en:
SILVA, Wellington Jefferson Oliveira da. Avaliação físico-química e quimiométrica de combustível aeronáutico: uma abordagem acerca da estabilidade após estocagem e com adição de adulterantes. 2021. 101f. Dissertação (Mestrado em Química) - Centro de Ciências Exatas e da Terra, Universidade Federal do Rio Grande do Norte, Natal, 2021.
Autor
Silva, Wellington Jefferson Oliveira da
Resumen
The fuel is necessary for the evaluation of quality issues, QAV, due to its great
importance, demand for use and for safety, it needs a physical-chemical property
before being inserted in the market, in order to certify that of the product and guarantee
that its characteristics meet the standards imposed by the National Agency of
Petroleum, Biofuels and Natural Gas – ANP. However, even with production control,
adulteration processes can guarantee the process of this product in its quality
distribution. This sought to assess the impact of quality keros with quality, tampered
with when necessary. The investigation was carried out using two methodologies. The
first one occurred by simulating the adult who wanted the combination, as a
combination of kerosene combination 0% (v/characterization) by comparing
comparison chemicals, freezing content, soot point, total sulfur content, distillation
curvature, specific gravity, soot point, soot point, tolerance and corrosivity. In the
second, spectroscopic methods associated with chemometric techniques were used.
Therefore, the tampering of the QAV was simulated in different lighting products,
ranging from 5 to 60% (v/v). As a sample they were by infrared spectroscopic
techniques (MIR/NIR) during a period that extended for 60 days. The data obtained
later through chemometric analysis techniques (PCA), analysis-model of
discriminatory analysis of curves obtained with linear alternation (MCR-LDS) in order
to obtain an analysis model that could predict the presence of adults and the amount
present of this in falling kerosene. The results. However, the chemometric techniques
used in this work were able to identify the presence of MCR-ALS.