article
Kinetics and thermodynamics of Cu(II) adsorptionon oil shale wastes
Registro en:
0378-3820
10.1016/j.fuproc.2007.07.003
Autor
Melo, Marcus Antônio de Freitas
Pimentel, Patrícia Mendonça
Melo, Dulce Maria de Araújo
Assunção, Ary Leonídio do Carmo
Henrique, Daniele de Macedo
Silva Júnior, Carlos Neco da
González, Gaspar
Resumen
The oil shale waste material, retorted shale, was utilized as an adsorbent for Cu(II) removal from aqueous solution. The kinetics and thermodynamic adsorption was investigated during a series of batch adsorption experiments. The removal efficiency was controlled by solution pH, temperature, initial ion concentration and contact time. Two simple kinetic models, pseudo-first-and second-order, were used to investigate the adsorption mechanisms. The pseudo-second-order chemical reaction kinetics provides the best correlation with the experimental data. Langmuir and Freundlich models were used to fit the equilibrium data, which showed that Langmuir best-fitted these data. Thermodynamic parameters such as free energy, enthalpy and entropy were calculated to predict the nature of the adsorption process