Samples of Gd-doped ceria (GDC, Ce0.9Gd0.1O1.95) with eutectic mixtures of Na2CO3 and Li2CO3 (NLC), or K2CO3, Na2CO3 and Li2CO3 (KNLC) as sintering aids (5 mol%) were studied against pure GDC and cobalt doped GDC. The former electrolytes reached densifications in excess of 95% when sintered at 1100 C, values comparable to pure GDC sintered at 1500 C, and more than 20% higher than for GDC sintered at 1100 C. X-ray diffraction powder patterns showed only typical GDC peaks without any noticeable lattice modification and microstructural analysis suggested a homogeneous distribution of residual amounts of sintering aids. The electrical properties of all materials were studied by impedance spectroscopy in air from 200 to 750 C. Materials with NLC and KNLC showed a total ionic conductivity matching pure GDC at 600 C. Hebb-Wagner polarization measurements, used to assess the impact of sintering aids on the nand p-type electronic conductivity of GDC (600e750 C) showed that NLC and KNLC additions lower the p-type conductivity of GDC while Co additions have the opposite effect. The efficacy of alkali metal salts to produce ceria-based electrolytes with competitive ionic and electronic transport properties is exposed2030-12