Dba-free palladium intermediates of the Heck-Matsuda reaction

dc.contributorUniversidade Estadual de Campinas (UNICAMP)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade Federal de Minas Gerais (UFMG)
dc.date.accessioned2014-05-27T11:29:32Z
dc.date.accessioned2022-10-05T18:50:46Z
dc.date.available2014-05-27T11:29:32Z
dc.date.available2022-10-05T18:50:46Z
dc.date.created2014-05-27T11:29:32Z
dc.date.issued2013-05-28
dc.identifierOrganic and Biomolecular Chemistry, v. 11, n. 20, p. 3277-3281, 2013.
dc.identifier1477-0520
dc.identifierhttp://hdl.handle.net/11449/75444
dc.identifier10.1039/c3ob40142a
dc.identifierWOS:000318306400002
dc.identifier2-s2.0-84877257398
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3924379
dc.description.abstractThe dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(ii) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested. © 2013 The Royal Society of Chemistry.
dc.languageeng
dc.relationOrganic and Biomolecular Chemistry
dc.relation3.423
dc.relation1,281
dc.rightsAcesso restrito
dc.sourceScopus
dc.subjectCatalytic cycles
dc.subjectHeck-matsuda reactions
dc.subjectPalladium intermediates
dc.subjectPalladium species
dc.subjectTransient complexes
dc.subjectWacker-type reactions
dc.subjectChemistry
dc.subjectPositive ions
dc.subjectReaction intermediates
dc.titleDba-free palladium intermediates of the Heck-Matsuda reaction
dc.typeArtigo


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