dc.contributorUniversidade Federal do Rio de Janeiro (UFRJ)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade de São Paulo (USP)
dc.contributorCNRS
dc.date.accessioned2014-05-20T15:32:32Z
dc.date.accessioned2022-10-05T17:10:46Z
dc.date.available2014-05-20T15:32:32Z
dc.date.available2022-10-05T17:10:46Z
dc.date.created2014-05-20T15:32:32Z
dc.date.issued2008-04-01
dc.identifierElectrochimica Acta. Oxford: Pergamon-Elsevier B.V. Ltd, v. 53, n. 10, p. 3670-3679, 2008.
dc.identifier0013-4686
dc.identifierhttp://hdl.handle.net/11449/41411
dc.identifier10.1016/j.electacta.2007.11.077
dc.identifierWOS:000254354300014
dc.identifier2797127887030838
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3912326
dc.description.abstractHydrogen interaction with oxide films grown on iron electrodes at open circuit potential (E-oc) and in the passive region (+0.30 V-ECS) was studied by chronopotentiometry, chronoamperometry and electrochemical impedance spectroscopy techniques. The results were obtained in deaerated 0.3 mol L-1 H3BO3 + 0.075 mol L-1 Na2B4O7 (BB, pH 8.4) solution before, during and after hydrogen permeation. The iron oxide film modification was also investigated by means of in situ X-ray absorption near-edge spectroscopy (XANES) and scanning electrochemical microscopy (SECM) before and during hydrogen permeation. The main conclusion was that the passive film is reduced during the hydrogen diffusion. The hydrogen permeation stabilizes the iron surface at a potential close to the thermodynamic water stability line where hydrogen evolution can occur. The stationary condition required for the determination of the permeation parameters cannot be easily attained on iron surface during hydrogen permeation. Moreover, additional attention must be paid when obtaining the transport parameters using the classical permeation cell. (c) 2007 Elsevier Ltd. All rights reserved.
dc.languageeng
dc.publisherPergamon-Elsevier B.V. Ltd
dc.relationElectrochimica Acta
dc.relation5.116
dc.relation1,439
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectiron
dc.subjectoxide layer stability
dc.subjectEIS
dc.subjectin situ XANES hydrogen permeation
dc.subjectin situ SECM hydrogen permeation
dc.titleChanges on iron electrode surface during hydrogen permeation in borate buffer solution
dc.typeArtigo


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