Mono and dinuclear Pd(II) complexes with pyrazole and imidazole-type ligands

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:32:31Z
dc.date.accessioned2022-10-05T17:10:37Z
dc.date.available2014-05-20T15:32:31Z
dc.date.available2022-10-05T17:10:37Z
dc.date.created2014-05-20T15:32:31Z
dc.date.issued2009-07-01
dc.identifierJournal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 97, n. 1, p. 57-60, 2009.
dc.identifier1388-6150
dc.identifierhttp://hdl.handle.net/11449/41395
dc.identifier10.1007/s10973-008-9667-x
dc.identifierWOS:000270840800010
dc.identifier7927677053650819
dc.identifier0000-0002-0057-7964
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3912310
dc.description.abstractThe cyanate-bridged cyclopalladated compound [Pd(C(2),N-dmba)(mu-NCO)](2) (dmba=N,N-dimethylbenzylamine) reacts in acetone with pyrazole (pz), 3,5-dimethylpyrazole (dmpz), imidazole (imz) and 2-methylimidazole (mimz) to give [Pd(2)(C(2),N-dmba)(2)(mu-NCO)(mu-pz)] (1), [Pd(2)(C(2),N-dmba)(2)(mu-NCO)(mu-dmpz)] (2), [Pd(C(2),N-dmba)(NCO)(imz)] (3) and [Pd(C(2),N-dmba)(NCO)(mimz)] (4), respectively. The compounds were characterized by elemental analysis, IR spectroscopy and TG. The thermal decomposition of the compounds occurs in three consecutive steps and the final decomposition products were identified as Pd(0) by X-ray powder diffraction. The thermal stability order of the complexes is 2 > 3 > 1 > 4.
dc.languageeng
dc.publisherSpringer
dc.relationJournal of Thermal Analysis and Calorimetry
dc.relation2.209
dc.relation0,587
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectcyclopalladated compounds
dc.subjectimidazoles
dc.subjectpyrazoles
dc.subjectspectroscopy
dc.subjectthermal analysis
dc.titleMono and dinuclear Pd(II) complexes with pyrazole and imidazole-type ligands
dc.typeArtigo


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