Synthesis, spectroscopic characterization and molecular modeling of a tetranuclear platinum(II) complex with thiazolidine-4-carboxylic acid

dc.contributorUniversidade Estadual de Campinas (UNICAMP)
dc.contributorCentro Univ Araraquara
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:30:26Z
dc.date.accessioned2022-10-05T16:59:15Z
dc.date.available2014-05-20T15:30:26Z
dc.date.available2022-10-05T16:59:15Z
dc.date.created2014-05-20T15:30:26Z
dc.date.issued2012-07-18
dc.identifierJournal of Molecular Structure. Amsterdam: Elsevier B.V., v. 1019, p. 21-26, 2012.
dc.identifier0022-2860
dc.identifierhttp://hdl.handle.net/11449/39816
dc.identifier10.1016/j.molstruc.2012.03.074
dc.identifierWOS:000305847200004
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3910870
dc.description.abstractThe synthesis, spectroscopic characterization and molecular modeling of a novel tetranuclear platinum(II) complex with thiazolidine-4-carboxylic acid (THC) are described. Elemental analysis is consistent with the composition PtCl2C4H7NO2S-H2O. Infrared (IR) spectroscopic results and solid-state C-13 and N-15 nuclear magnetic resonance (NMR) data indicate coordination of the ligand to Pt(II) through the nitrogen and sulfur atoms. The square planar geometry of the platinum(II) complex is completed by chlorine atoms. Density functional theory (OFF) suggests the formation of a tetrameric cluster as the most probable structure, where each THC molecule bridges between two metal centers. The compound is insoluble in water. (C) 2012 Elsevier B.V. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationJournal of Molecular Structure
dc.relation2.011
dc.relation0,409
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectThiazolidine-4-carboxylic acid
dc.subjectPlatinum(II) complex
dc.subjectInfrared spectroscopy
dc.subjectSolid-state NMR
dc.subjectMolecular modeling
dc.titleSynthesis, spectroscopic characterization and molecular modeling of a tetranuclear platinum(II) complex with thiazolidine-4-carboxylic acid
dc.typeArtigo


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