dc.contributor | Universidade Estadual Paulista (Unesp) | |
dc.contributor | Universidade Estadual de Maringá (UEM) | |
dc.contributor | Universidade de São Paulo (USP) | |
dc.contributor | BioTools Inc | |
dc.contributor | Syracuse Univ | |
dc.date.accessioned | 2014-05-20T14:21:12Z | |
dc.date.accessioned | 2022-10-05T15:21:34Z | |
dc.date.available | 2014-05-20T14:21:12Z | |
dc.date.available | 2022-10-05T15:21:34Z | |
dc.date.created | 2014-05-20T14:21:12Z | |
dc.date.issued | 2012-01-01 | |
dc.identifier | Organic & Biomolecular Chemistry. Cambridge: Royal Soc Chemistry, v. 10, n. 21, p. 4208-4214, 2012. | |
dc.identifier | 1477-0520 | |
dc.identifier | http://hdl.handle.net/11449/26341 | |
dc.identifier | 10.1039/c2ob25109d | |
dc.identifier | WOS:000303768700008 | |
dc.identifier | 0124211071790021 | |
dc.identifier | 1308042794786872 | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/3899286 | |
dc.description.abstract | The absolute configuration and solution-state conformers of three peperomin-type secolignans isolated from Peperomia blanda (Piperaceae) are unambiguously determined by using vibrational circular dichroism (VCD) spectroscopy associated with density functional theory (DFT) calculations. Advantages of VCD over the electronic form of CD for the analysis of diastereomers are also discussed. This work extends our growing knowledge about secondary metabolites within the Piperaceae family species while providing a definitive and straightforward method to assess the absolute stereochemistry of secolignans. | |
dc.language | eng | |
dc.publisher | Royal Soc Chemistry | |
dc.relation | Organic & Biomolecular Chemistry | |
dc.relation | 3.423 | |
dc.relation | 1,281 | |
dc.rights | Acesso restrito | |
dc.source | Web of Science | |
dc.title | VCD to determine absolute configuration of natural product molecules: secolignans from Peperomia blanda | |
dc.type | Artigo | |