Crystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O

dc.creatorPiro, Oscar Enrique
dc.creatorEcheverría, Gustavo Alberto
dc.creatorArrambide, Gabriel
dc.creatorGambino, Dinorah
dc.creatorBarán, Enrique José
dc.date2011
dc.date2019-10-29T12:54:27Z
dc.identifierhttp://sedici.unlp.edu.ar/handle/10915/84269
dc.identifierissn:0932-0776
dc.descriptionThe crystal and molecular structure of the [VO(DLmeth)(NH 2O)2]?H2O complex has been determined by X-ray diffraction methods (monoclinic, P21/c with a = 5.8138(2),b = 27.3496(8), c = 7.5663(2) Å , β = 103.059(3)°, and Z =4). The vanadium(V) cation is in a pentagonal bipyramidal environment axially coordinated to the oxo group and equatorially to two hydroxylamido groups in a side-on fashion. The fifth equatorial binding site and the other apical position are occupied by an N and an O atom, respectively, from the methioninate anion acting as a bidentate ligand.
dc.descriptionInstituto de Física La Plata
dc.descriptionCentro de Química Inorgánica
dc.formatapplication/pdf
dc.format752-754
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-sa/4.0/
dc.rightsCreative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.subjectQuímica
dc.subjectAmino Acid Complex
dc.subjectCrystal Structure
dc.subjectHydroxylamido Complex
dc.subjectOxovanadium(V)Complex
dc.titleCrystal and molecular structure of a new hydroxylamido/amino acid oxovanadium(V) complex, [VO(NH<SUB>2</SUB>O)<SUB>2</SUB>(DL-methioninato)]·H<SUB>2</SUB>O
dc.typeArticulo
dc.typeArticulo


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