Sodium titanate as basic catalyst in transesterification reactions

dc.contributorUniversidade Federal de São Carlos (UFSCar)
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade Estadual de Campinas (UNICAMP)
dc.contributorFed Technol Univ Parana UTFPR
dc.date.accessioned2014-12-03T13:08:38Z
dc.date.available2014-12-03T13:08:38Z
dc.date.created2014-12-03T13:08:38Z
dc.date.issued2014-02-01
dc.identifierFuel. Oxford: Elsevier Sci Ltd, v. 118, p. 48-54, 2014.
dc.identifier0016-2361
dc.identifierhttp://hdl.handle.net/11449/111422
dc.identifier10.1016/j.fuel.2013.10.036
dc.identifierWOS:000329116600008
dc.identifier6466841023506131
dc.identifier0000-0002-3823-0050
dc.description.abstractSodium titanate was synthesized by the sol-gel method and characterized using X-ray diffraction, thermogravimetry-mass spectrometry, atomic absorption spectroscopy, scanning electron microscopy, energy-dispersive X-ray analysis and nitrogen physisorption. The non-calcined material was active as a catalyst in transesterification reactions and showed high stability. An appreciable loss of activity on the fourth reuse was accompanied by the appearance of a new species of oxygen and segregated sodium, identified by X-ray photoelectron spectroscopy (XPS). The XPS spectrum showed that the basic nature of the framework oxygen was inferior to the original basicity, which explained the decline in catalytic activity. (C) 2013 Elsevier Ltd. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationFuel
dc.relation4.908
dc.relation1,891
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectSodium titanate
dc.subjectSol-gel
dc.subjectBasicity
dc.subjectTransesterification
dc.subjectHeterogeneous catalysis
dc.titleSodium titanate as basic catalyst in transesterification reactions
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución