Hydrogen bonding donation of N-methylformamide with dimethylsulfoxide and water

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-27T11:28:53Z
dc.date.available2014-05-27T11:28:53Z
dc.date.created2014-05-27T11:28:53Z
dc.date.issued2013-04-05
dc.identifierChemical Physics Letters, v. 565, p. 40-44.
dc.identifier0009-2614
dc.identifierhttp://hdl.handle.net/11449/75068
dc.identifier10.1016/j.cplett.2013.02.017
dc.identifierWOS:000316794700008
dc.identifier2-s2.0-84875439906
dc.description.abstract20% N-methylformamide (NMF) mixtures with water and with dimethylsulfoxide (DMSO) have been studied. A comparison between the hydrogen bonding (H-bond) donation of N-methylformamide with both solvents in the mixtures is presented. Results of radial distribution functions, pair distribution energies, molecular dipole moment correlation, and geometry of the H-bonded species in each case are shown. The results indicate that the NMF-solvent H-bond is significantly stronger with DMSO than with water. The solvation shell is best organized in the DMSO mixture than in the aqueous one. © 2013 Elsevier B.V. All rights reserved.
dc.languageeng
dc.relationChemical Physics Letters
dc.relation1.686
dc.relation0,656
dc.rightsAcesso restrito
dc.sourceScopus
dc.subjectH-bonded
dc.subjectMolecular dipole moment
dc.subjectN-methylformamide
dc.subjectPair distributions
dc.subjectRadial distribution functions
dc.subjectSolvation shell
dc.subjectMixtures
dc.subjectHydrogen bonds
dc.titleHydrogen bonding donation of N-methylformamide with dimethylsulfoxide and water
dc.typeArtículos de revistas


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