A 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomer

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:24:42Z
dc.date.available2014-05-20T15:24:42Z
dc.date.created2014-05-20T15:24:42Z
dc.date.issued2007-07-01
dc.identifierInorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 10, n. 7, p. 815-820, 2007.
dc.identifier1387-7003
dc.identifierhttp://hdl.handle.net/11449/35270
dc.identifier10.1016/j.inoche.2007.04.005
dc.identifierWOS:000247795000020
dc.identifier7927677053650819
dc.identifier0000-0002-0057-7964
dc.description.abstractThe new complex [Cu(NCS)(2)(pn)] (1) (pn = 1,3-propanediamine) has been synthesized and characterized by elemental analysis, infrared and electronic spectroscopy. Single crystal X-ray diffraction studies revealed that complex 1 is made up of neutral [Cu(NCS)(2)(pn)] units which are connected by mu-1,3,3-thiocyanato groups to yield a 2D metal-organic framework with a brick-wall network topology. Intermolecular hydrogen bonds of the type NH...SCN and NH...NCS are also responsible for the stabilization of the crystal structure. (c) 2007 Elsevier B.V. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationInorganic Chemistry Communications
dc.relation1.810
dc.relation0,430
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectsupramolecular chemistry
dc.subjectself-assembly
dc.subjectcopper(II)
dc.subjectcoordination polymer
dc.subjecthydrogen bonding
dc.titleA 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomer
dc.typeArtículos de revistas


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